Ahstrati-'The electrocatalytic reduction of 1,2-dibromoethane and tetrabromoethane with CoTPP in DMF solutions containing 0.1 M TRAP was investigated at a Pt ultramicroelectrode. The experimental results indicated that CoTPP obviously exhibited catalytic activity for 1,2dibromoethane and tetrabromoe
✦ LIBER ✦
The application of an ultramicroelectrode in homogeneous catalytic reaction—Part I. General characteristic of a homogeneous catalytic reaction at an ultramicroelectrode with arbitrary geometry under steady state
✍ Scribed by Shaojun Dong; Guangli Che
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 254 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
A general characteristic of the electrochemical process coupling with a homogeneous catalytic reaction at an ultramicroelectrode under steady state is described. It was found that the electrochemical process coupling with homogeneous catalytic reaction has a similar steady state voltammetric wave at an ultramicroeleetrode with arbitrary geometry. A method of determination for the kinetic constant of homogeneous catalytic reaction at an ultramieroelectrede with arbitrary geometry is proposed
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