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The application of an ultramicroelectrode in homogeneous catalytic reaction—Part I. General characteristic of a homogeneous catalytic reaction at an ultramicroelectrode with arbitrary geometry under steady state

✍ Scribed by Shaojun Dong; Guangli Che


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
254 KB
Volume
37
Category
Article
ISSN
0013-4686

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✦ Synopsis


A general characteristic of the electrochemical process coupling with a homogeneous catalytic reaction at an ultramicroelectrode under steady state is described. It was found that the electrochemical process coupling with homogeneous catalytic reaction has a similar steady state voltammetric wave at an ultramicroeleetrode with arbitrary geometry. A method of determination for the kinetic constant of homogeneous catalytic reaction at an ultramieroelectrede with arbitrary geometry is proposed


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✍ Guangli Che; Shaojun Dong 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 397 KB

Ahstrati-'The electrocatalytic reduction of 1,2-dibromoethane and tetrabromoethane with CoTPP in DMF solutions containing 0.1 M TRAP was investigated at a Pt ultramicroelectrode. The experimental results indicated that CoTPP obviously exhibited catalytic activity for 1,2dibromoethane and tetrabromoe