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The applicability of the concept of free volume to processes of glass transition in incompatible polymer mixtures

✍ Scribed by Yu.S. Lipatov; V.A. Vilenskii


Book ID
118964861
Publisher
Elsevier Science
Year
1975
Weight
470 KB
Volume
17
Category
Article
ISSN
0032-3950

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The magnitude of the activation energy for diffusion, ED. is shown to be inversely dependent on the fractional free volume of the polymer above Tg. From the proportionality of ED above and below Tg, the magnitude of El, below T, is also inversely dependent on the free volume in that temperature rang

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## Abstract Theories based on free‐volume concepts have been developed to characterize the self and mutual‐diffusion coefficients of low molecular weight penetrants in rubbery and glassy polymer‐solvent systems. These theories are applicable over wide ranges of temperature and concentration. The ca