The Antimony-Based Type I Clathrate Compounds Cs8Cd18Sb28 and Cs8Zn18Sb28

✍ Scribed by Yi Liu; Li-Ming Wu; Long-Hua Li; Shao-Wu Du; John D. Corbett; Ling Chen

• Publisher: John Wiley and Sons
• Year: 2009
• Tongue: English
• Weight: 620 KB
• Volume: 48
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.200806158

✦ Synopsis

Abstract

In phase: The title compounds lie in a new region of phase space for such a structure, and have stoichiometries in accord with a classical Zintl phase formulation. The small semiconductor gaps indicated by DFT calculations are also supported by their diamagnetic susceptibilities.magnified image