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The Anomeric Linkage of Streptose in Streptomycin and Bluensomycin

✍ Scribed by McGilveray, Iain J.; Rinehart, Kenneth L.

Book ID
127164072
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
286 KB
Volume
87
Category
Article
ISSN
0002-7863

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Determination of both linkage position a
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## Abstract Negative‐ion electrospray mass spectrometry was used to determine directly both glycosidic linkage position and anomeric configuration in the complete glucopyranosyl disaccharide series without the need for derivatization or tandem mass analysis. A series of empirical criteria were deve