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The anodic fluorosulphonation of some saturated organic compounds

✍ Scribed by J.P. Coleman; D. Pletcher

Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
163 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis

Although peroxydisulphuryldifluoride was first prepared a number of years ago', its potential as a reagent in synthesis has not previously been realised and, indeed, the only 2 reactions which have been reported are those in the vapour phase with perfluoroolefins .

In this paper we describe some reactions between peroxydisulphuryldifluoride and some saturated organic molecules, namely methane, acetic acid, propionic acid and acetone, in anhydrous fluorosulphonic acid; the products are fluorosulphonate esters, species which are likely to be

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