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The anodic dissolution of iron in acidic acetonitrile-water solutions

✍ Scribed by Elisabet Ahlberg; Mick Friel

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 815 KB
Volume: 34
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(89)87084-7

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✦ Synopsis

The anodic dissolution of pure iron in acetonitrile-water solutions with varying concentrations of acetonitrile and varying pH has been investigated. Potentiodynamic measurements with different sweep rates have been done. Acetonitrile was shown to act as an interface inhibitor for the dissolution of iron at low overpotential, almost entirely inhibiting the I, reaction. The alternative dissolution path, I;, which appears in the potential region of I, and involves acetonitrile adsorption was investigated. The dissolution reaction at higher overpotentials, I,, was found to be largely uninfluenced, although acetonitrile is adsorbed on the surface.

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