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The Anion Radical of [18]Annulene

✍ Scribed by Kurth, Todd L.; Brown, Eric C.; Hattan, Chris M.; Reiter, Richard C.; Stevenson, Cheryl D.

Book ID: 127343260
Publisher: American Chemical Society
Year: 2002
Tongue: English
Weight: 82 KB
Volume: 106
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp013524+

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## Abstract The radical anions of heptalene and of 1, 7‐methano‐[12]annulene are generated by metal reduction and characterized by means of their ESR‐spectra. Whereas the neutral hydrocarbons are π‐bond localized their corresponding radical anions turn out to be π‐bond delocalized. This could be de