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The Anion of a Phenyltris(alkylamino)phosphonium (PhTAP) Salt as a Chelating Ligand: Synthesis and X-ray Crystal Structure of a 16-Electron Ruthenium(II) Organometallic Complex

โœ Scribed by Bailey, Philip J.; Grant, Keith J.; Parsons, Simon


Book ID
127166835
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
77 KB
Volume
17
Category
Article
ISSN
0276-7333

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## Abstract The complex __trans__โ€[RuCl~2~{ฮบ^2^โ€__P__,__P__โ€(__S__)โ€peap}~2~] (1) has been stereoselectively prepared by the treatment of a stoichiometric mixture of complex [RuCl~2~(DMSO)~4~] (DMSO = dimethyl sulfoxide) and (__S__)โ€peap [(__S__)โ€peap = (โˆ’)โ€__N__,__N__โ€bis(diphenylphosphanyl)โ€(__S_