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The Anharmonic Vibrational Potential and Relaxation Pathways of the Amide I and II Modes of N -Methylacetamide †

✍ Scribed by DeFlores, Lauren P.; Ganim, Ziad; Ackley, Sarah F.; Chung, Hoi Sung; Tokmakoff, Andrei

Book ID
120171534
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
488 KB
Volume
110
Category
Article
ISSN
0022-3654

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Electrostatic origin of the cooperative
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✍ Hajime Torii 📂 Article 📅 2005 🏛 Elsevier Science 🌐 English ⚖ 169 KB

The electric fields operating among the molecules in the oligomers of N-methylacetamide are analyzed to see the reasons for the cooperative effect on the CaO bond lengths and the diagonal force constants in the vibrational subspace of the amide I mode. It is suggested that the following three factor