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The Anatomy of the Energetics of Molecular Recognition by Calorimetry: Chiral Discrimination of Camphor by α-Cyclodextrin

✍ Scribed by Franz P. Schmidtchen

Book ID
101368818
Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
152 KB
Volume
8
Category
Article
ISSN
0947-6539

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Manifestation of chiral recognition of c
Manifestation of chiral recognition of camphor enantiomers by α-cyclodextrin in longitudinal and transverse relaxation rates of the corresponding 1:2 complexes and determination of the orientation of the guest inside the host capsule
✍ Waldemar Anczewski; Helena Dodziuk; Andrzej Ejchart 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 92 KB

## Abstract The 1:2 complexes of camphor enantiomers with α‐cyclodextrin in ^2^H~2~O manifest differences in longitudinal and transverse relaxation rates of camphor methyl protons owing to chiral recognition. The relaxation data obtained at two magnetic fields were quantitatively analyzed using the