concentration of 2 mg./litre, reduction is complete in 5 min. and the reduction time is not materially reduced by higher molybdenum concentrations. The effect of the residual iron colour on the calibration graph is shown in Fig. and it will be observed that the effect is more pronounced in the pres
The analysis of anhydrous hydrogen fluoride
β Scribed by Cook, C. D. ;Findlater, F. G.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1947
- Weight
- 466 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0368-4075
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β¦ Synopsis
procedure is d scribed for 6 e analysis of anhydrous hydrogen fluoride containinJ the following impurities ; sulphur dioxide, hydrogen sulphide, sulphuric acid, fluorosihc acid and water. The use of glacial acetic acid as a diluent for the anhydrous acid slmplrfies both the technique and the apparagpreviously required when water was used as the diluent. * Note.-In order to illus!rate the precision of the methods described, :: . so* .. I0 (evaporation)
π SIMILAR VOLUMES
## Abstract The method of fluorination using antimony pentachloride and anhydrous hydrogen fluoride^1^ has, by a simple modification, been extended to allow the almost quantitative conversion of the βC,Cl~3~ radical to βCF~3~, in chloroform, carbon tetrachloride, asβtetrachloroethane, and methyl ch
difluoro-x : z-dichloroethane (675 9.) and hydrogen fluoride (120 g.), to the spent fluorinating agent. Methy&umofm.-Methylchlorofom (800 g.) antimony pentachloride (300 g.) and hydrogen fluoride (460 g.) were heated to a temperature of 30-40" during about 45 minutes, while the pressure was adjuste