The analysis of alkyl thiocyanates and isothiocyanates by NMR
β Scribed by A. Mathias
- Publisher
- Elsevier Science
- Year
- 1965
- Tongue
- French
- Weight
- 229 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
The mechanism of isomerization of allyl thiocyanate to allyl isothiocyanate has been investigated both experimentally and theoretically. The kinetic study indicates that the reaction is unimolecular and is not ionic. The entropy of activation suggests strongly that the mechanism involves a cyclic tr
**Ein Verfahren fΓΌr die gleichzeitige Gewinnung von Alkylisothiocyanaten und Thiolen** Aus primΓ€ren Alkylaminen wurden Ethylβ, Butylβ, Isobutylβ und __n__βDodecyldithiocarbamate **2** hergestellt. Letztere lassen sich leicht zu den Isothiocyanaten **3** und Thiolen **4** pyrolysieren. Die Massenspe