Anaerobic rupture of the benzoic acid ring was investigated, Carbon 4 was converted primarily to carbon dioxide. Following ring rupture during methane fermentation, propanoic acid is an intermediate, and carbon 4 of benzoate becomes its carboxyl.
The anaerobic decomposition of benzoic acid during methane fermentation
β Scribed by C. L. Keith; R. L. Bridges; L. R. Fina; K. L. Iverson; J. A. Cloran
- Book ID
- 104765571
- Publisher
- Springer
- Year
- 1978
- Tongue
- English
- Weight
- 423 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0302-8933
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β¦ Synopsis
A possible pathway for the anaerobic utilization of benzoic acid by a methanogenic consortium is suggested. Cyclohexane carboxylic acid and 1-cyclohexene-1-carboxylic acid have been identified as intermediates before ring rupture. Suprisingly, 3-cyclohexene-1-carboxylic acid interferes with utilization of other cyclic acids. In addition, isobutyric acid or short chain acids containing carbon-carbon double bonds could not be used without induction periods of a week or longer. A number of volatile fatty acids (heptanoic, valeric, butyric, propanoic, and acetic) have been identified and are suggested intermediates.
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