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The Aminomethylation of Olefins. V. A New Synthesis of 4-Phenylpyridine and Related Compounds

โœ Scribed by Schmidle, Claude J.; Mansfield, Richard C.

Book ID
115488887
Publisher
American Chemical Society
Year
1956
Tongue
English
Weight
528 KB
Volume
78
Category
Article
ISSN
0002-7863

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Mesyl guaiacol: a versatile intermediate
Mesyl guaiacol: a versatile intermediate for the synthesis of 5-aminomethyl guaiacol and related compounds
โœ Nicolas Bensel; Virginie Pevere; Jean Roger Desmurs; Alain Wagner; Charles Miosk ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 128 KB

An original synthetic pathway for the preparation of 5-substituted guaiacol derivatives is described. This method relies on the deactivation of the phenol group by converting it into the corresponding mesyl ester. Amidomethylation reactions lead to regioselective C C bond formation at the 5-position