The amide acetal condensation of propargyl alcohols: synthesis of γ-keto esters and silyl allenes under mild conditions

✍ Scribed by Kathlyn A. Parker; Raymond W. Kosley Jr.

• Publisher: Elsevier Science
• Year: 1976
• Tongue: French
• Weight: 200 KB
• Volume: 17
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)93726-2

✦ Synopsis

Xn this communication we report the first example of a Claisen rearrangement involving an enamine as the ally1 double bond and a general, high yield synthesis of silyl allenes.