✦ LIBER ✦

THE ALLYLIC REARRANGEMENT OF CROTYL BROMIDE AND CROTYLMAGNESIUM BROMIDE

✍ Scribed by Young, William G.; Prater, Arthur N.

Book ID: 127310874
Publisher: American Chemical Society
Year: 1932
Tongue: English
Weight: 138 KB
Volume: 54
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01340a506

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📜 SIMILAR VOLUMES

Allylic Rearrangements. II. Crotyl and M

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The Preparation of Crotylmagnesium Bromi

The Preparation of Crotylmagnesium Bromide. The Effect of Solvents on the Yield of Crotyl and Allylmagnesium Bromides 1

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Allylic Rearrangements. VII. The Action

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Allylic Rearrangements. IV. The Composit

Allylic Rearrangements. IV. The Composition of Butenyl Bromides Prepared from Crotyl Alcohol and Methylvinylcarbinol 1,2

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Allylic Rearrangements. XV. The Carbonat

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Allylic substitution/rearrangement of cannabinoids with trimethylsilyl bromide

✍ Herbert H. Seltzman; M.Anthony Moody; Mosammat K. Begum 📂 Article 📅 1992 🏛 Elsevier Science 🌐 French ⚖ 183 KB

## Trimethylsilyl bromide (TMSBr) in the presence of catalytic ZnZ2 induces facile substitution of allylic acetates to the bromides with or without rearrangement as governed by product stability. This was applied to the preparation of a key intermediate employed in the synthesis of important cannabi