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The Alkali Metal Catalyzed Reactions of ι-Phenyl-1-alkenes. The Novel Cyclizations of 6-Phenyl-1-hexene and 7-Phenyl-1-heptene 1,2

✍ Scribed by Pines, Herman; Sih, Norman C.; Lewicki, Edward


Book ID
121375460
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
677 KB
Volume
30
Category
Article
ISSN
0022-3263

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1-Methyl(or phenyl)-5-(penta-O-acetyl-d-
✍ Manuel Gómez-Guillén; José María Lassaletta Simon 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 887 KB

The title hept-I -enitol( 2) reacted with aldehyde methyl(or phenyl)hydrazones in refluxing methanol or butyl acetate to give I-methyl(or phenyl)-5-(penta-O-acetyl-~-~~u~u~f~~-pentitol-l-yl)pyrazoles in good (for I-methylpyrazoles) or moderate yields (for I-phenylpyrazolcs). The 0-deacetylated produ