## Abstract The preparation and stabilisation of miniemulsions using in situ generated surfactants is described. Neutralising a water‐soluble base with an oil‐soluble long‐chain acid instantaneously generates in situ surfactants at the oil/water interface, resulting in a rapid homogenisation/polyme
The Advantages of In Situ Surfactant Generation for Miniemulsions
✍ Scribed by Ula El-Jaby; Michael Cunningham; Timothy F. L. McKenna
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 156 KB
- Volume
- 31
- Category
- Article
- ISSN
- 1022-1336
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✦ Synopsis
Abstract
The stabilisation of miniemulsions using an in situ generated surfactant is presented. This surfactant, prepared from of a water‐soluble base and an oil‐soluble long chain acid was successfully used to create stable miniemulsions with up to 60 vol.‐% organic phase. It is shown that the creation of a surface active species at the oil–water interface allowed stable miniemulsions to be generated more rapidly than when using conventional surfactant. In addition, polymerised miniemulsions exhibited less secondary nucleation when in situ surfactants were used.
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## Abstract A novel method for synthesis of ultrafine polymeric nanoparticles of diameters less than 20 nm has been developed. The method is based on miniemulsion polymerization exploiting combination of the in situ surfactant generation approach (whereby the surfactant is formed at the oil–water i