The adsorption of n-butylamine at polycrystalline silver electrodes in aqueous solution
β Scribed by N.A. Hampson; J.B. Lee; J.R. Morley; B. Scanlon
- Publisher
- Elsevier Science
- Year
- 1970
- Weight
- 113 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0022-0728
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Differential capacity of polycrystalline silver electrode in aqueous KF solutions containing thiourea (TU) of concentrations from 0.001 to 0.25 mol drnm3 has been measured by the previously described potentiostatic method CM. Brzostowska-Smolska et al., J. electroanal. Chem. 89, 389 (1978)]. The TU
alkaline solutions, when the potential of the silver electrode is more positive than -450 mV vs see, thiourea undergoes decomposition and a sparingly soluble silver sulfide film forms as a product of the accompanying anodic reaction. These processes are controlled by convective diffusion and depend
Surhce-enkmced Rrtman spectra are reported from pyridme in ~,~-d~e~~lfor~~mide at a silver electrode. Potentialand time-dependent resnfts are presented and discussed in terms of the electrode surface morphology.