✍ Scribed by Stefan Minc; Maria Jurkiewicz-Herbich
No coin nor oath required. For personal study only.
Previously I we studied the effect of temperature on the adsorption of C1-ions on mercury from aqueous HC1 solution in the 25°-60°C region. The analysis of the results suggested that the specific adsorption of C1-ions decreases with increasing temperature; in particular this was indicated by a linear decrease in q~l-values with temperature at constant qM. The influence of temperature on the molecular properties of the inner layer proved to be insignificant, except for a small increase in both capacitance components q,K i and qK i with increasing temperature; the thickness ratio values (XE--X1)/X 2 were practically independent of temperature at constant charge of mercury surface.
In the present investigation of the specific adsorption properties for C1-ions at t = 0 ° C, deviations from the previously observed trends have been noted ; especially that the adsorbed charge q~-is slightly lower than that at t = 25 ° C for small positive qM values (Fig. ). These are accompanied by a shift of the potential of zero charge 20-
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~-Adsorption on polarized Hg electrode of formate ions from aqueous solutions of pore HCOONa \* ~kelltial capscity =s=IIccBIyn txwasstudied.Aoionspe&ca&o+onwasindimtedbythe catho+~0fpo~tial0f~chargewith inukase in bulk4ectroiytt activity. Variation of charge due to ~ur&&eacessof$od&miono(T'+ 2, F)an
## Introduction This paper is concerned with two aspects of the properties of the electrodesolution interface. Firstly, it is a study involving two non-aqueous solvents, propylene carbonate (PC) and dimethylsulphoxide (DMSO). Both of these solvents have been the subject of a number of recent elect