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The Addition of Thiyl Radicals to Allenic Hydrocarbons 1

✍ Scribed by Jacobs, Thomas L.; Illingworth, G. E.


Book ID
120712048
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
973 KB
Volume
28
Category
Article
ISSN
0022-3263

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Free-radical reactions of allene the int
✍ H. J. van der Ploeg; J. Knotnerus; A. F. Bickel πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 479 KB

## Abstract The free‐radical addition of 1‐propanethiol, benzenethiol (thiophenol) and α‐toluenethiol (benzyl mercaptan) to allene in benzene solution has been investigated. At high allene/thiol ratios the two sulfides resulting from the addition of one mole of RSH to allene (isopropenyl‐SR and al