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The addition of methyllithium to 2,2,4,4-tetramethylcyclobutan-1-one-3-thione. The generation and capture of a bishomoenolate anion.

✍ Scribed by Paul G. Gassman; Michael J. Mullins


Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
206 KB
Volume
21
Category
Article
ISSN
0040-4039

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The fragmentation behaviour of ten 3,4-disubstituted 1,2,4-oxadiazole-5(4H)-thiones and seven 3,4-disubstituted 1,2,4-thiadiazole-5(4H)-ones studied here confirmed the earlier observations about the partial rearrangement of the former after ionization into the latter before further fragmentation. In