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The Addition of Methyl Radicals to Ethylene, Propylene, the Butenes and Higher 1-Olefines

✍ Scribed by Buckley, R. P.; Szwarc, M.

Book ID
120144700
Publisher
The Royal Society
Year
1957
Tongue
English
Weight
616 KB
Volume
240
Category
Article
ISSN
0962-8444

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πŸ“œ SIMILAR VOLUMES

Ene reactions of olefins, part II. The a
Ene reactions of olefins, part II. The addition of ethylene to propylene and to isobutene and the addition of propylene to propylene
✍ C. Richard; M. H. Back πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 651 KB

## Abstract The pyrolysis of ethylene–propylene and ethylene–isobutene mixtures has been studied in a static system over the temperature range of 682°–754Β° K and for initial pressures of each olefin of 33–300 torr. The following molecular ene reactions were observed and the rate constants measured:

Ene reactions of olefins. I. The additio
Ene reactions of olefins. I. The addition of ethylene to 2-butene and the decomposition of 3-methylpentene-1
✍ C. Richard; G. Scacchi; M. H. Back πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 639 KB

## Abstract The pyrolysis of ethylene–butene‐2 mixtures has been studied in a static system over the temperature range of 689°‐754Β°k and for initial pressures of each olefin of 20–200 torr. The two main addition products were cyclopentene and 3‐methylpentene‐1. Kinetic evidence indicated that cyclo