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The Addition of Methyl Radicals to Benzene

✍ Scribed by Levy, M.; Steinberg, M.; Szwarc, M.

Book ID
125953680
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
254 KB
Volume
76
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

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The reaction of methyl radicals (Me) with hexafluoroacetone (HFA), generated from ditertiary butyl peroxide (dtBP), was studied over the temperature range of 402-433 K and the pressure range of 38-111 torr. The reaction resulted in the following displacement process taking place: where TFA refers t

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## Abstract The addition of methyl radicals to hexafluoropropylene has been studied over the temperature range 81°–203Β°C using a mass‐balance technique involving the photolysis of biacetyl in the presence of hexafluoropropylene–isobutane mixtures. For the reaction the rate constant is given by th

Kinetics of gas-phase addition reactions
Kinetics of gas-phase addition reactions of methyl radicals. I. Addition to ethylene, acetylene, and benzene
✍ Pauline M. Holt; J. Alistair Kerr πŸ“‚ Article πŸ“… 1977 πŸ› John Wiley and Sons 🌐 English βš– 643 KB

The reactions have been studied by a mass-balance method involving the photolysis of small amounts of biacetyl in the presence of a large excess of isobutane containing a small proportion of the unsaturated substrate. The following Arrhenius parameters have been derived: Temperature Reaction E log A