THE ADDITION OF GRIGNARD REAGENTS TO 1,2,3,4-TETRAPHENYLFULVENE
β Scribed by FUSON, REYNOLD C.; YORK, OWEN.
- Book ID
- 127094981
- Publisher
- American Chemical Society
- Year
- 1953
- Tongue
- English
- Weight
- 348 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Grignard compounds (organomagnesium halides) are among the longest-known organometallic reagents and have found a plethora of applications in organic synthesis. [2] In particular, they are used for additions to polarized or polarizable carbon-heteroatom multiple bonds. However, they are less suitabl
Diketones have been always perceived as a practical source of stabilized carbanions owing to the enhanced acidity of the active methylene hydrogen atoms.['] The alkylation of 1,3-diketones can be carried out with almost complete regio-and stereocontrol of the products.121 Every attempt at attacking