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The Addition of Acylcobalt Carbonyls to α,β-Unsaturated Carbonyl Compounds. 1-Acyloxy-π-allylcobalt Tricarbonyl Derivatives

✍ Scribed by Heck, Richard F.


Book ID
126206501
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
464 KB
Volume
87
Category
Article
ISSN
0002-7863

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Enantioselective Copper-Catalyzed 1,4-Ad
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The enantioselective copper-catalyzed 1,4-addition of Grignard reagents to a$-unsaturated carbonyl compounds was studied with the following Cu' compounds as catalyst precursor and 1,2 : 5,6-di-0 -isopropylidene-3thio-a -o-glucofuranose (Hsiig) as chiral ligand: CuI, iodo[bis(dibutylsulfide)]copper(I