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The addition of 2-lithio phenylthioacetonitrile to α,β-unsaturated cyclic ketones

✍ Scribed by Nai-yi Wang; Shin-san Su; Li-ying Tsai

Publisher: Elsevier Science
Year: 1979
Tongue: French
Weight: 269 KB
Volume: 20
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)86080-9

No coin nor oath required. For personal study only.

✦ Synopsis

The Michael reaction is one of the most important processes in synthetic organic chemistry'. It provides the basis for the Robinson annelation and many 2 other chain-elongation reactions . If performed intramolecularly, the reaction becomes avaluable tool for the construction of complex ring systems 3 . The scope of the reaction is further expanded by the recent findings that organocuprates 4

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