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The active sites of chloroperoxidase and cytochrome P-450-CAM: Comparative spectroscopic and ligand binding properties

✍ Scribed by John H. Dawson; Masanori Sono; Lowell P. Hager


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
324 KB
Volume
79
Category
Article
ISSN
0020-1693

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## Abstract __The effects of site‐specific mutation of the axial cysteine (C357M) to a methionine residue in cytochrome P450cam on the enzyme’s coordination geometry and redox potential have been investigated. The absorption spectra of the haem centre in the C357M mutant of the enzyme showed close