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The Activation of Carbon−Chlorine Bonds in Per- and Polyfluoroalkyl Chlorides: DMSO-Induced Hydroperfluoroalkylation of Alkenes and Alkynes with Sodium Dithionite

✍ Scribed by Long, Zheng-Yu; Chen, Qing-Yun

Book ID
120014040
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
231 KB
Volume
64
Category
Article
ISSN
0022-3263

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ChemInform Abstract: The Activation of Carbon—Chlorine Bonds in Per- and Polyfluoroalkyl Chlorides: DMSO-Induced Hydroperfluoroalkylation of Alkenes and Alkynes with Sodium Dithionite.
✍ Zheng-Yu Long; Qing-Yun Chen 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 44 KB 👁 1 views

The Activation of Carbon-Chlorine Bonds in Per-and Polyfluoroalkyl Chlorides: DMSO-Induced Hydroperfluoroalkylation of Alkenes and Alkynes with Sodium Dithionite. -In DMSO, addition reactions of perfluoroalkyl chlorides to alkenes or alkynes occur smoothly in the presence of Na 2 S 2 O 4 and NaHCO