THE ACTIVATION ENERGY FOR THE DISPROPORTIONATION OF THE HO 2 RADICAL IN ACID SOLUTIONS 1
β Scribed by Bielski, Benon H. J.; Saito, Eiichi
- Book ID
- 120987768
- Publisher
- American Chemical Society
- Year
- 1962
- Tongue
- English
- Weight
- 398 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0022-3654
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π SIMILAR VOLUMES
We review and discuss kinetic studies of the disproportionation reaction of iodous acid (HIO 2 ) in the presence of excess of Hg 2+ -ions. The reactions are followed at different temperatures in water solution with strongly defined acidity. The rate constants of disproportionation are determined bet
Since the activation energy for the reaction R H + 0 2 -+ R . + HO; is very close to its endothermicity, the R-H bond energy can be calculated from the activation energy for free radical formation by the reaction R H + 0 2 . The relation between Ei and QR-H was found empirically after measuring Ei b