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The Action of Soybean Lipoxygenase-1 on 12-Iodo- cis -9-octadecenoic Acid: The Importance of C(11)−H Bond Breaking †

✍ Scribed by Clapp, Charles H.; McKown, Jeremy; Xu, Hui; Grandizio, Anna Marie; Yang, Guang; Fayer, Jessica

Book ID
126111642
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
93 KB
Volume
39
Category
Article
ISSN
0006-2960

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## Abstract Acid treatment of 9__exo__‐methyl‐__anti__^10,11^‐tricyclo[4.2.1.1^2,5^]deca‐3,7‐diene‐9__endo__, 10__endo__‐diol (**8**) leads to the two isomeric pentacyclic ethers **7** and **9** by intramolecular nucleophilic substitution of a protonated OH‐group with participation of a C,C‐double