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The Action of Methylmagnesium Iodide on Methyl α-Phenylcinnamate and a Synthesis of 1,1-Dimethyl-2-phenylindene

✍ Scribed by Koelsch, C. F.; Johnson, Paul R.


Book ID
126790818
Publisher
American Chemical Society
Year
1943
Tongue
English
Weight
309 KB
Volume
65
Category
Article
ISSN
0002-7863

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[1,2]-hydride shifts in the reaction of
✍ Masajiro Kawana; Sakae Emoto 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 221 KB

Despite the extensive amount of research on nonenzymatic [1,2]-hydride shifts.2 there have been particularly few reports on similar transfers related to carbohydrates.3 We wish to report here the novel example of the stereoselective [1,2]-hydride shifts which occured in the reactions of methyl 3-0-m