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THE ACONITE ALKALOIDS. THE STRUCTURE OF HETISINE

โœ Scribed by Solo, A. J.; Pelletier, S. W.


Book ID
126042316
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
259 KB
Volume
81
Category
Article
ISSN
0002-7863

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A hexacyclic compound 1, which carries an almost full structure of the hetisine skeleton lacking only the six-membered ring with an exo methylene group, was synthesized by applying an acetal-ene reaction on 5 for the bond formation of C-14 and C-20 as well as stereoselective hydrocyanation reaction