The acid catalyzed ring opening reaction of episulfoxides
โ Scribed by Kiyosi Kondo; Akira Negishi; Gen-ichi Tsuchihashi
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 111 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
While the direct opening of the L&one of erythromy& A by hydroxide to give the sxo acid has so far proved elusive, two types of base catalyzed reactions which lead to rupture of the ring with formation of the Cl carboxylate have been d&cove& in solvent P translactonization-elimination process R"!c v
A6struct; Eu(dpm), [dpm: dipivaloylmetbanate] catalyzes the ring-opening reaction of epoxides with acyl halides affording the correspondii 2-habakyl esters. The stewochemical course was confirmed as frms-addition in the case of the reaction of cyclohexene oxide. 0 I 998 Elsevier Smnce Ltd.