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The acid-catalyzed rearrangement and disproportionation of aromatic hydrazo compounds. Comments on the paper by V. O. Lukashevich.

✍ Scribed by H.J. Shine

Publisher: Elsevier Science
Year: 1967
Tongue: French
Weight: 274 KB
Volume: 8
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)89734-3

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✦ Synopsis

In a recent paper (1) Lukashevich has summarized his views on the roarrangement and disproportionation of aromatic hydrazo compounds. These views deny the validity of current interpretations of the mechanism of the acidcatalyzed benzidine rearrangement, interpretations which have been based on extensive kinetic studies by several groups. Lukashevich's views on acidcatalyzed disproportionation are also in conflict with kinetic evidence, and, like those on rearrangement are in error. These views are discussed and contrasted with experimental facts in the following pages.

Rearranqement.

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