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The Acid-Catalyzed Nitramine Rearrangement. I. The Products of Rearrangement of N-Nitro-N-methylaniline

โœ Scribed by White, William N.; Lazdins, Dagnija.; White, Hilda S.


Book ID
126899823
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
576 KB
Volume
86
Category
Article
ISSN
0002-7863

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By-products in the rearrangement of N-me
โœ Zdzislaw Daszkiewicz; Ewa Nowakowska; Janusz B. Kyziol ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 598 KB

N-MethyI-N-phenylnitramine was rearranged in the aqueous dioxane -sulphuric acid mixture to 2-nitro-and 4-nitro-N-methylanilines. The isomer ratio was independent of the acidity within the range of-0.3 > I4o > -2.8. Some by-products were isolated and identified e.g. N-methyl-Nnitrosoaniline, its 2-n