THE ACCELERATIVE ORTHO EFFECT. II. THE ORIENTATION IN THE MERCURATION OF NITROBENZENE
β Scribed by OGATA, YOSHIRO.; TSUCHIDA, MASARU.
- Book ID
- 126973778
- Publisher
- American Chemical Society
- Year
- 1955
- Tongue
- English
- Weight
- 371 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0022-3263
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## Abstract ^13^C NMR chemical shifts of 22 __ortho__βsubstituted nitrobenzenes are reported. Except for those on Cβ3 and Cβ5, the effects of the interacting nitro group and the substituent are nonβadditive. The chemical shifts of the __ipso__, __ortho__ and __para__ carbons in the spectra and thos
An abundant loss of hydroxyl in decompositions of ortho-substituted nitroarene cations is commonly observed when the substituent contains one or more labile hydrogen atoms. The major loss of hydroxyl also takes place from many but not all of the corresponding molecular anions. Data are reported for