𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The absorption kinetics of photoreductions of anthraquinone and 1-chloroanthraquinone by triethylamine in toluene and ethanol

✍ Scribed by Kumao Hamanoue; Kazuo Yokoyama; Yöichi Kajiwara; Masaki Kimoto; Toshihiro Nakayama; Hiroshi Teranishi

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
324 KB
Volume
113
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The photoreduction of the title compounds by triethylamine in toluene and ethanol was found to originate via formation of an exciplex between the lowest triplet anthraquinones and triethylamine. This complex changed to a contact ion pair followed by proton transfer, generating anthrasemiquinone radicals and triethylamine radical.

📜 SIMILAR VOLUMES

Primary processes in the photoreduction
Primary processes in the photoreduction of 1-chloro- and 1,8-dichloro-anthraquinones in ethanol studied by laser spectroscopy
✍ Kumao Hamanoue; Kazuo Yokoyama; Yōichi Kajiwara; Kazuo Nakajima; Toshihiro Nakay 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 409 KB

The hydrogen-atom abstraction of the title compounds from ethanol was found IO originate from the It slave in spite of the Inked nn\*--nn\* or nn\* chractcr of the lowest triplet state (Tt). No evidence for electron transfer from ethanol IO the Tt state of a-1131o~enoa~~tilraquinoncs WIS obtained.

Kinetics of toluene and sulfur compounds
Kinetics of toluene and sulfur compounds removal by means of an integrated process involving the coupling of absorption and biodegradation
✍ Guillaume Darracq; Annabelle Couvert; Catherine Couriol; Abdeltif Amrane; Pierre 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 123 KB

## Abstract **BACKGROUND:** Scrubbing using an organic solution instead of an aqueous solution could be a useful way to improve the removal of hydrophobic compounds. Absorption of toluene, dimethyldisulfide (DMDS) and dimethylsulfide (DMS) in an organic solution (di‐2‐ethylhexyladipate—DEHA), follo

Kinetics and mechanism of the reactions
Kinetics and mechanism of the reactions of the superoxide ion in solutions. II. The kinetics of protonation of the superoxide ion by water and ethanol
✍ I. B. Afanas′ev; N. S. Kuprianova 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 237 KB

The rate constants for the protonation of "free" (that is, solvated) superoxide ions by water and ethanol are equal to 0.5-3.5 X lO-~M-l.s-' in DMF and AN at 20'. It has been found that the protonation rates for the ion pairs of 0; with the BudN+ cation are much slower than those for "free" 0,. It i