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THE ABSOLUTE RATE CONSTANTS IN THE POLYMERIZATION OF LIQUID VINYL ACETATE

โœ Scribed by Bartlett, Paul D.; Swain, C. Gardner


Book ID
127100349
Publisher
American Chemical Society
Year
1945
Tongue
English
Weight
239 KB
Volume
67
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


Effect of solvent on the rate constants
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Measurements were made of the value of the lumped kinetic constant k p /k t 0.5 of vinyl acetate in different solvents and with different initiators. This quantity was evaluated using the well-known conversion vs. time approach in dilute solutions using both azo-bis-isobutyronitrile and benzoyl pero

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Claims have recently been made that absolute rate constants for chain propagation of the unassociated active centers can be made in systems where a high degree of association is present. Anionic polymerization of styrene in nonpolar solvents with lithium as counterion is a typical case. The conditio