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The absolute rate constant of propagation of the free living polystyrene ion, and the dissociation constant of the ∼∼S, NA ion pair

✍ Scribed by Toelle, K. J. ;Smid, J. ;Szwarc, M.


Publisher
Wiley (John Wiley & Sons)
Year
1965
Tongue
English
Weight
242 KB
Volume
3
Category
Article
ISSN
0449-2986

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## Abstract The lithium imide 3 is slightly more basic than lithium bis(tri‐methylsilyl)amide (5c) in THF solution. Based on a reported p__K__~a~ value for hexamethyldisilazane (4c) and assuming the simplest form of ion‐pair equilibration in eq. 1, the apparent p__K__~a~ = 26.5 was determined for t