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The Absolute Configuration of Gambieric Acids A–D, Potent Antifungal Polyethers, Isolated from the Marine Dinoflagellate Gambierdiscus toxicus

✍ Scribed by Akio Morohashi; Masayuki Satake; Hiroshi Nagai; Yasukatsu Oshima; Takeshi Yasumoto

Book ID
108370972
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
163 KB
Volume
56
Category
Article
ISSN
0040-4020

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✍ Akio Morohashi; Masayuki Satake; Takeshi Yasumoto 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 172 KB

The axial C6-OH group in gambierol isolated from the dinoflagellate, Gambierdiscus toxicus, was inverted to equatorial disposition and esterified with (S)-and (R)-MTPA. NMR analysis of these esters established S configuration at C6, thus allowing determination of the absolute configuration of the wh

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