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The absolute configuration of cis, trans- 1,5-cyclooctadiene. Determination of enantiomeric purity without knowledge of the maximum optical rotation and without the aid of an auxiliary optically active substance.

✍ Scribed by J. Leitich


Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
222 KB
Volume
19
Category
Article
ISSN
0040-4039

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✦ Synopsis


Stiftstrasse 34-36, D-4330 Miilheim a.d. Ruhr (-)-cis,trans-1,5-cyclooctadiene (l), prepared by resolution of the racemic diene (11, was transformed into (+)-trans-1,2_cyclooctanediol (3) according to scheme I. R-(-)-l_ OS04 (IS, 2S)-(+I-2 \n H#d ,*\\O H