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The absolute configuration of avarol, a rearranged sesquiterpenoid hydroquinone from a marine sponge

โœ Scribed by de Rosa, Salvatore; Minale, Luigi; Riccio, Raffaele; Sodano, Guido


Book ID
121000318
Publisher
Royal Society of Chemistry
Year
1976
Weight
948 KB
Volume
13
Category
Article
ISSN
1472-7781

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6S,10S)-3,10- Dimethyl-7,11-dimethylidenespiro[5,5]undec-2-en-4-one (1), a new rearranged chamigrane-type sesquiterpenoid with two sp 2 -hybridized carbons in ฮฑ-positions to the spiro-atom, was isolated from the alcoholic extract of the sea hare Aplysia sp. and its structure and absolute configurati