The absolute configuration and optical purity of (−)- and (+)-1,2:4,5-di-O-cyclohexylidene-myo-inositols
✍ Scribed by Rajindra Aneja; Sarla G. Aneja; Alejandro Parra
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 137 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0957-4166
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
An efficient method for the resolution of 1,2:4,5-di-O-isopropylidene-myo-inositol has been developed. The diketal was converted to diastereomeric 3,6-di-O-mandelates by the reaction with (S)-O-acetylmandeloyl chloride. Both the diastereomers could be separated by sequential crystallization in multi
## Abstract Chemical resolution of a versatile starting material, 1,2‐__O__cyclohexylidene‐3,4‐__O__‐(tetraisopropyldisiloxane‐1,3‐diyl)__myo__‐inositol, which is used to access naturally occurring inositol phosphates and phosphatidylinositol phosphates, is described. Starting from both D‐ and L‐en