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The ab initio analysis of molecular geometry and force fields in H3XOXH3 (X = C, Si) series

✍ Scribed by I.S. Ignatyev


Book ID
107803082
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
713 KB
Volume
172
Category
Article
ISSN
0022-2860

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The reaction of [(C3Ph3)Ni (PPh3),]C104 with P (CH2CH2PPh2)3 (pp3) and NaBPh4 yields the [(C3Ph3)Ni (pp3)]BPh4-complex. After long exposure of the solution of this compound in acetone/butanol to the air a new derivative [(C3Ph3)-Ni (pp2po)]BPh4 .0.5 C4H90H, where pp2po is (Ph,PCH2CH2),P (CH2CH2POPh2