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The [3,3′-Co(1,2-C2B9H11)2]– anion as a platform for new materials: synthesis of its functionalized monosubstituted derivatives incorporating synthons for conducting organic polymers

✍ Scribed by Llop, Jordi; Masalles, Carlos; Viñas, Clara; Teixidor, Francesc; Sillanpää, Reijo; Kivekäs, Raikko


Book ID
118119878
Publisher
Royal Society of Chemistry
Year
2003
Tongue
English
Weight
199 KB
Volume
4
Category
Article
ISSN
1477-9226

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Synthesis and Structure of [Sn4Se11]6–,
✍ Anja Loose; William S. Sheldrick 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 205 KB 👁 2 views

Reaction of A 2 CO 3 (A = K, Rb) with Sn and Se in an H 2 O/CH 3 OH mixture at 115±130 °C affords the isotypic selenidostannates(IV) A 6 Sn 4 Se 11 ´x H 2 O (A = K, x = 8) 1 and 2 whose discrete [Sn 4 Se 11 ] 6± anions each contain two corner-bridged ditetrahedral [Sn 2 Se 6 ] 4± species. Similar re