The 248 nm photodecomposition of hexahydro-1,3,5-trinitro-1,3,5-triazine
โ Scribed by Christos Capellos; Panos Papagiannakopoulos; Yu-Lon Liang
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 458 KB
- Volume
- 164
- Category
- Article
- ISSN
- 0009-2614
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## Abstract ^14^Cโlabeled hexahydroโ1,3,5โtrinitroโ1,3,5โtriazine (2, RDX) was prepared by nitrolysis of hexahydroโ1,3,5โtripropionylโ1,3,5โtriazine (1) for bioenvironmental studies. 1 was synthesized from paraformaldehyde and propionitrile by a modified method reported earlier.
The thermal decomposition of RDX has been investigated in a static system below its melting point at ~ 195ยฐ(?. "the initial decomp<~,ition of RDX takes place in the vapor phase. Ilydroxymethyl [ormamidc and polymeric materials tbrmed from hydroxymethyl formamide have been shown to be major products.