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The 1E−2g ← 1A−1g transition in benzene

✍ Scribed by A.M. Taleb; I.H. Munro; J.B. Birks


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
298 KB
Volume
21
Category
Article
ISSN
0009-2614

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📜 SIMILAR VOLUMES


The 1B1u ← 1A1g 0—0 transition in crysta
✍ J.B. Birks; E. Pantos; T.D.S. Hamilton 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 257 KB

The transition linewidth AE in crystal C I' 6 J6, C6D6 and symC6H3D3 has been measured as a function of temperature T from 4.2 to 135"K, and it extrapolates to a common value of tie = 50 cm-' at 0°K. In CbH6 aE = (50+ 7T"2) cm-', indicative of strong cxciton-phonon couplin g, and there is a line shi

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✍ C.E. Otis; S.G. Grubb; K.S. Haber; A.C. Albrecht 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 289 KB

The three-photon spectrum of the 'Bzu-l Alg transition in gas-phase benzene has been recorded and analyzed. Though formally allowed at the three-photon level, this transition is seen to be entirely vibronically induced. The last unknown e2g vibration (vg) in the 'Bzu state is identified.

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✍ Rich Mathies; A.C. Albrecht 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 349 KB

The change in the in-plane polxizability of benzene uPon excitation from the 'Atg state to the 'Bzu state is deduced from electric field perturbation experiments. These are carried out on the First vibronically allowed band of benzene in a rigid solution of 3.methylpentane (3.XIP) at 7?K. The obser

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✍ E. Pantos; T.D.S. Hamilton 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 368 KB

Low temperature absorption spectra of benzene films were observed in the 'B,, -'Alg trxnsition region. T11e origins of the two progressions of the totally symmetric vibration IJT(~,~) are assigned to the crystal-field-induced O-O transition nnd to the false origin 0 + ~~lg(e2~).