The 195Pt chemical shifts and 195Pt15N coupling constants for cis-diammineplatinum(II) complexes
✍ Scribed by M Chikuma; R.J Pollock
- Publisher
- Elsevier Science
- Year
- 1982
- Weight
- 272 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0022-2364
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## Abstract The values ^n^__J__ (^195^Pt, ^14^N) are shown to be measurable directly from the ^195^Pt spectrum for a variety of complexes containing nitrogen ligands. The sample temperature can play an important role in determining the width of the ^195^Pt signal. ^195^Pt chemical shifts for the co
## Abstract The ^295^Pt and ^205^Tl NMR chemical shifts of the complexes [(NC)~5~PtTl(CN)~__n__~]^__n__−^ __n__=0–3, and of the related system [(NC)~5~PtTlPt(CN)~5~]^3−^ have been computationally investigated. It is demonstrated that based on relativistically optimized geometries, by applying an