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The 185 nm photolysis of 1,4-dioxan in aqueous solution in the presence of N2O:N2 formation via dioxan photoionization or photoexcitation?

✍ Scribed by Heinz-Peter Schuchmann; Clemens Von Sonntag


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
958 KB
Volume
52
Category
Article
ISSN
1010-6030

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In aqueous solution, bis(nucleoside) complexes formed by the reaction of cis-[Pt(NH3)2(H2O)2]2+ with an excess of either adenosine (ado) or a mixture of adenosine and guanosine (guo) undergo a slow N7--> N1 linkage isomerisation in the adenine moiety. The isomerisation probably involves the breaking